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The boiling point of methane is −161.5°C while that of neon is −264°C.

Why is the boiling point of methane greater than that of neon?

AMolecules of methane have a larger surface area to form stronger intermolecular forces than those of neon
Correct. The tetrahedral CH4 molecule has a larger surface area than a spherical Ne atom. Larger surface area increases polarisability and the strength of London dispersion forces, raising the boiling point.
BA molecule of methane has more electrons than an atom of neon.
Incorrect. CH4has 6 (C) + 4×1 (H) = 10 electrons; Ne also has 10 electrons. They have the same electron count, so this cannot explain the difference in boiling point.
CA molecule of methane has a greater relative molecular mass than an atom of neon.
DMolecules of methane form hydrogen bonds, but those of neon do not.
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